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KMID : 1059520130570050599
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Journal of the Korean Chemical Society
2013 Volume.57 No. 5 p.599 ~ p.605
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Solvent-Free Synthesis of Some1-Acetyl Pyrazoles
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Thirunarayanan Ganesamoorthy
Sekar Krishnamoorthy Guna
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Abstract
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Some N-acetyl pyrazoles including 1-(3-(3,4-dichlorophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole- 1-yl) ethanones have been synthesised by solvent free cyclization cum acetylation of chalcones like substituted styryl 3,4- dichlorophenyl ketones using hydrazine hydrate and acetic anhydride in presence of catalytic amount of fly-ash: H2SO4 catalyst. The yield of these N-acetyl pyrazole derivatives are more than 75%. The synthesised N-acetyl pyrazoline derivatives were characterized by their physical constants and spectral data
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KEYWORD
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Solvent-free cyclization cum acetylation, N-acetyl pyrazoles, IR, NMR spectra
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